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Krishna Kumar Damodaran - Professor

Krishna Kumar Damodaran

–

School of Engineering and Natural Sciences

Krishna Kumar Damodaran

Professor

Inorganic Chemistry and Supramolecular Chemistry

Phone
525 - 4846
Email
krishna [at] hi.is

Unit
Faculty of Physical Sciences
Website
http://uni.hi.is/krishna/
Published Work
Krishna Kumar Damodaran - published work

Curriculum Vitae
Krishna Kumar Damodaran - Curriculum Vitae
ORCID site
https://orcid.org/0000-0002-9741-2997
Research portal – Krishna Kumar Damodaran

Published works

2024

AsymPol-TEKs as efficient polarizing agents for MAS-DNP in glass matrices of non-aqueous solventsPhysical Chemistry Chemical Physics
Nanoscale assembly of enantiomeric supramolecular gels driven by the nature of solventsNanoscale

2023

Synthesis, spectral characterization, and catalytic efficiency of aroylhydrazone-based Cu(ii) complexesNew Journal of Chemistry
Stimuli-Responsive Properties of Supramolecular Gels Based on Pyridyl-N-oxide AmidesGels
The Role of Functional Groups in Tuning the Self‐Assembly Modes and Physical Properties of Multicomponent GelsChemPlusChem

2022

Cytotoxic effects of halogenated tin phosphinoyldithioformate complexes against several cancer cell linesDalton Transactions
Highly Efficient Polarizing Agents for MAS‐DNP of Proton‐Dense Molecular SolidsAngewandte Chemie International Edition
Analysing the role of anions in the synthesis of catalytically active urea-based MOFsDalton Transactions
Synthesis of new chiral Mn(iii)–salen complexes as recoverable and reusable homogeneous catalysts for the asymmetric epoxidation of styrenes and chromenesNew Journal of Chemistry
Highly Efficient Polarizing Agents for MAS‐DNP of Proton‐Dense Molecular SolidsAngewandte Chemie

2021

Enantioselective Gel Phase Synthesis of Metal–Organic MaterialsAngewandte Chemie International Edition
Crystal Habit Modification of Metronidazole by Supramolecular Gels with Complementary FunctionalityCrystal Growth & Design
Solid-State Structural Transformation and Photoluminescence Properties of Supramolecular Coordination CompoundsSymmetry
Evaluating the role of a urea-like motif in enhancing the thermal and mechanical strength of supramolecular gelsCrystEngComm
Enantioselective Gel Phase Synthesis of Metal–Organic MaterialsAngewandte Chemie
Making and Breaking of Gels: Stimuli-Responsive Properties of Bis(Pyridyl-N-oxide Urea) GelatorsMolecules

2020

Synthesis and characterization of asymmetric [Mo2O2(μ-S)2(S2)(L)] complexes (L = bipy, en, dien) and their heterogeneous reaction with propylene sulfideInorganica Chimica Acta
Syntheses, spectral aspects and biological studies of bromide and azide bridged box dimer copper(II) complexes of an NNO donor aroylhydrazoneInorganica Chimica Acta
Role of N–Oxide Moieties in Tuning Supramolecular Gel-State PropertiesGels
Metal complexation induced supramolecular gels for the detection of cyanide in waterSupramolecular Chemistry
Reaction Chemistry of the syn-[Mo2O2(μ-S)2(S2)(DMF)3] Complex with Cyanide and Catalytic Thiocyanate FormationInorganic Chemistry
Unraveling the self-assembly modes in multi-component supramolecular gels using single crystal X-ray diffractionChemistry of Materials

2019

Tuning Gel State Properties of Supramolecular Gels by Functional Group ModificationMolecules

2018

Enhanced Mechanical and Thermal Strength in Mixed-Enantiomers-Based Supramolecular GelLangmuir
Crystal habit modification of Cu(ii) isonicotinate–N-oxide complexes using gel phase crystallisationNew Journal of Chemistry
Cytotoxic activity of novel organotin compounds against different cancer cell linesExperimental and Molecular Therapeutics

2017

Pharmaceutical polymorph control in a drug-mimetic supramolecular gelChemical Science
Electron beam induced deposition of silacyclohexane and dichlorosilacyclohexane; the role of dissociative ionization and dissociative electron attachment in the deposition process. Beilstein Journal of Nanotechnology

2016

Anion responsive and morphology tunable tripodal gelatorsRSC Advances

2015

Selective gelation of N-(4-pyridyl)nicotinamide by copper(ii) saltsCrystEngComm
Fluorous 'ponytails' lead to strong gelators showing thermally induced structure evolutionSoft Matter

2014

Supramolecular gel phase crystallization: orthogonal self-assembly under non-equilibrium conditionsChemical Society Reviews

2012

Fluorescent Acridine-Based Receptors for H(2)PO(4)(-)Journal of Organic Chemistry
Dirhodium Paddlewheel with Functionalized Carboxylate Bridges: New Building Block for Self-Assembly and Immobilization on Solid SupportInorganic Chemistry

2011

Zinc(II) coordination polymers with pseudopeptidic ligandsCrystengcomm
Targeting of anionic membrane species by lanthanide(III) complexes: towards improved MRI contrast agents for apoptosisChemical Communications
Cu(II) coordination polymers derived from bis-pyridyl-bis-urea ligands: synthesis, selective anion separation and metallogelationCurrent Science
Supramolecular Synthons in Designing Low Molecular Mass Gelling Agents: L-Amino Acid Methyl Ester Cinnamate Salts and their Anti-Solvent-Induced Instant GelationChemistry-an Asian Journal

2010

Coordination polymers derived from a bis-pyridyl-bis-amide ligand: Supramolecular structural diversities and anion binding propertiesInorganica Chimica Acta
Recyclable Dirhodium Catalysts Embedded in Nanoporous Surface-Functionalized Organosilica Hosts for Carbenoid-Mediated Cyclopropanation ReactionsChemcatchem
3,3 '-{Ethane-1,2-diylbis carbonylbis(azanediyl) }dipyridinium tetrachloridoplatinate(II)Acta Crystallographica Section E-Structure Reports Online

2009

Exploring the effect of chain length of bridging ligands in coordination complexes and polymers derived from mixed ligand systems of pyridylnicotinamides and dicarboxylatesInorganica Chimica Acta
DNA binding and cleavage properties of a newly synthesised Ru(II)-polypyridyl complexDalton Transactions
Metal-organic frameworks derived from bis-pyridyl-bis-amide ligands : Effect of positional isomerism of the ligands, hydrogen bonding backbone, counter anions on the supramolecular structures and selective crystallization of the sulfate anionCrystengcomm
Hexa-mu-chlorido-hexachlorido(eta(6)-hexamethylbenzene)trialuminium(III) lanthanum(III) benzene solvateActa Crystallographica Section E-Structure Reports Online
Microporous Nanotubular Self-Assembly of a Molecular ChairCrystal Growth & Design
Substitution of trans ligands in mu-oxo-bis(mu-acetato)diruthenium(III) complexes: Synthesis and kinetic studiesInorganica Chimica Acta

2008

An easy access to an organometallic low molecular weight gelator: a crystal engineering approachTetrahedron Letters
X-ray crystallographic investigations of an azacryptand and its bis-protonated salt: Interactions of acyclic water trimer and C-H center dot center dot center dot pi interactions in T-shaped benzene dimerSynthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
Zn(II) metal-organic frameworks (MOFs) derived from a bis-pyridyl-bis-urea ligand: effects of crystallization solvents on the structures and anion binding propertiesCrystengcomm
Ligating topology and counter anion controlled formation of discrete metallo-macrocycle and 2D corrugated sheet in coordination compounds derived from a bis-pyridyl-bis-amide ligand and Cd (II)saltsInorganic Chemistry Communications

2007

Composites of N,N '-bis-(pyridyl) urea-dicarboxylic acid as new hydrogelators - a crystal engineering approachTetrahedron
Metalloporphyrin-based inclusion materials: Exploiting ligating topologies and hydrogen-bonding backbones in generating new supramolecular architecturesInorganic Chemistry
Preferential binding of the magnesium ion by anthraquinone based chromogenic receptorsPolyhedron
Supramolecular structural diversities in the metal-organic frameworks derived from pyridylamide ligands: studying the effects of ligating topologies, hydrogen bonding backbone of the ligands and counter anionsCrystengcomm
Role of positional isomers on receptor-anion binding and evidence for resonance energy transferTetrahedron
Rugby-ball-shaped sulfate-water-sulfate adduct encapsulated in a neutral molecular receptor capsuleInorganic Chemistry
Remarkably stable porous assembly of nanorods derived from a simple metal-organic frameworkCrystal Growth & Design
Photochromism of arylchromenes: Remarkable modification of absorption properties and lifetimes of o-quinonoid intermediatesOrganic Letters
Generation of Ir-Sn and Rh-Sn bonds from the oxidative addition of tin(IV) halides to Ir(mu-Cl)(1,5-COD) (2) and Rh(mu-Cl)(1,5-COD) (2)Journal of Organometallic Chemistry
Isomerism in coordination complexes and polymers derived from bispyridylurea ligands: Effect of solvents, conformational flexibility, and positional isomerism of the ligandsCrystal Growth & Design
Conformation dependent network structures in the coordination polymers derived from pyridylisonicotinamides, carboxylates and Co(II): Entrapment of (H(2)O) 14 water cluster of an unprecedented topologyCrystengcomm

2006

Exploring hydrogen-bond capable backbone and ligating topologies: Co(II) coordination polymers derived from mixed ligand systemsJournal of Molecular Structure
Solid state structural evidence of chloroform-benzene-chloroform adduct trapped in hexaanthryl octaaminocryptand channelsJournal of the American Chemical Society
N-H center dot center dot center dot Cl-2-M synthon as a structure-directing tool: Crystal structures of some perchlorometallatesCrystal Growth & Design
Interfacial electron transfer between the photoexcited porphyrin molecule and TiO2 nanoparticles: Effect of catecholate bindingJournal of Physical Chemistry B
Exploring conformationally flexible hydrogen-bond-functionalized ligand and counter anions in metal-organic frameworks of Cu(II)New Journal of Chemistry
Hydrogen-bonded microporous network, helix and 1-D zigzag chains in MOFs of Zn(II): studying the effects of ligating topologies, hydrogen bonding backbone and counter-anionsCrystengcomm
Ultrafast dynamics and excited state deactivation of Ru(bpy)(2)Sq (+) and its derivativesJournal of Physical Chemistry B
One-dimensional chains, two-dimensional corrugated sheets having a cross-linked helix in metal-organic frameworks: Exploring hydrogen-bond capable backbones and ligating topologies in mixed ligand systemsCrystal Growth & Design

2005

First snapshot of a nonpolymeric hydrogelator interacting with its gelling solventsChemical Communications
Mixed-ligand complexes of ruthenium(II) containing new photoactive or electroactive ligands: synthesis, spectral characterization and DNA interactionsJournal of Biological Inorganic Chemistry
How Robust is N-H….Cl2—Cu synthon? Crystal structures of some perchlorocupratesCrystal Growth and Design
Urea and thiourea based efficient colorimetric sensors for oxyanionsTetrahedron Letters
Strongly coupled ruthenium-polypyridyl complexes for efficient electron injection in dye-sensitized semiconductor nanoparticlesJournal of Physical Chemistry B
Counteranion-controlled water cluster recognition in a protonated octaamino cryptandInorganic Chemistry
From diamondoid network to (4,4) net: Effect of ligand topology on the supramolecular structural diversityInorganic Chemistry
Synthesis, characterization, physicochemical, and photophysical studies of redox switchable NIR dye derived from a ruthenium-dioxolene-porphyrin systemInorganic Chemistry

2004

Efficient and simple colorimetric fluoride ion sensor based on receptors having urea and thiourea binding sitesOrganic Letters
Nonpolymeric hydrogelators derived from trimesic amidesChemistry of Materials
Nonpolymeric hydrogelator derived from N-(4-pyridyl)isonicotinamideLangmuir

Keywords for Specialisation:

Catalysis and supramolecular gels

Functional properties of coordination polymers/MOFs

Anion recognition of biologically relevant compounds

Anticancer drugs

Crystallography

CO2 Converstion